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Recharge Wrap-up: Ferrock a carbon-negative cement substitute, Audi makes e-diesel

Wed, Apr 22 2015 A cement alternative uses recycled materials and traps CO2 rather than producing it. Invented by David Stone at the University of Arizona, Ferrock uses recycled steel dust and glass to produce a substance stronger than conventional concrete. Cement has a high carbon footprint from the high heat needed to process the limestone. Ferrock needs no such heat, and it actually uses CO2 to harden, making it, as Stone calls it, a carbon-negative material. Learn more in the video above, see the transcript at PBS NewsHour and read more at Green Car Reports.

Teslarati offers a detailed rundown of Tesla's new Valet Mode feature for the Model S. Part of the Firmware 6.2 update, Valet Mode allows the owner to disable certain performance features and block personal information when letting someone else drive the car. It limits the car's to speed to 70 miles per hour, and caps output at 80 kW. It can also disable mobile app access, Homelink, Bluetooth and wifi and the "Places" function, which stores addresses for you. The folks at Teslarati did find some shortcomings in the new feature, though. Read more at Teslarati.

Audi has produced its first batch of e-diesel made from water and CO2. The fuel is made by reacting hydrogen from the water with CO2 to make long-chain hydrocarbon compounds called "blue crude." That can then be refined similarly to crude oil to make e-diesel, which is a fuel free from sulfur and aromatic hydrocarbons. That e-diesel can be used on its own, or mixed with fossil fuel diesel to power a vehicle. "In developing Audi e-diesel we are promoting another fuel based on CO2 that will allow long-distance mobility with virtually no impact on the climate," says Audi Head of Sustainable Product Development Reiner Mangold. Read more in the press release below.
Fuel of the future: Research facility in Dresden produces first batch of Audi e-diesel

- The verdict: Pilot plant produces high-quality diesel fuel
- No need for mineral oil: e-diesel made from water, CO2 and green power
- Minister Wanka: "Synthetic diesel using CO2 is a huge success"

Audi has taken another big step in the development of new, CO2 neutral fuels: A pilot plant in Dresden has started production of the synthetic fuel Audi e diesel.

After a commissioning phase of just four months, the research facility in Dresden started producing its first batches of high-quality diesel fuel a few days ago. To demonstrate its suitability for everyday use, Federal Minister of Education and Research Prof. Dr. Johanna Wanka put the first five liters into her official car, an Audi A8 3.0 TDI clean diesel quattro*, this Tuesday. "This synthetic diesel, made using CO2, is a huge success for our sustainability research. If we can make widespread use of CO2 as a raw material, we will make a crucial contribution to climate protection and the efficient use of resources, and put the fundamentals of the "green economy" in place," declared Wanka.

The Dresden energy technology corporation sunfire is Audi's project partner and the plant operator. It operates according to the power-to-liquid (PtL) principle and uses green power to produce a liquid fuel. The only raw materials needed are water and carbon dioxide. The CO2 used is currently supplied by a biogas facility. In addition, initially a portion of the CO2 needed is extracted from the ambient air by means of direct air capturing, a technology of Audi's Zurich-based partner Climeworks.

Reiner Mangold, Head of Sustainable Product Development at Audi, sees Audi e-diesel and Audi e-fuels in general as an important component that complements electric mobility: "In developing Audi e-diesel we are promoting another fuel based on CO2 that will allow long-distance mobility with virtually no impact on the climate. Using CO2 as a raw material represents an opportunity not just for the automotive industry in Germany, but also to transfer the principle to other sectors and countries."

Production of Audi e-diesel involves various steps: First, water heated up to form steam is broken down into hydrogen and oxygen by means of high-temperature electrolysis. This process, involving a temperature in excess of 800 degrees Celsius, is more efficient than conventional techniques because of heat recovery, for example. Another special feature of high-temperature electrolysis is that it can be used dynamically, to stabilize the grid when production of green power peaks.

In two further steps, the hydrogen reacts with the CO2 in synthesis reactors, again under pressure and at high temperature. The reaction product is a liquid made from long-chain hydrocarbon compounds, known as blue crude. The efficiency of the overall process – from renewable power to liquid hydrocarbon – is very high at around 70 percent. Similarly to a fossil crude oil, blue crude can be refined to yield the end product Audi e-diesel. This synthetic fuel is free from sulfur and aromatic hydrocarbons, and its high cetane number means it is readily ignitable. As lab tests conducted at Audi have shown, it is suitable for admixing with fossil diesel or, prospectively, for use as a fuel in its own right.

The Federal Ministry of Education and Research is supporting the sunfire project, which started in May 2012. Construction work on the facility in Dresden-Reick kicked off in July 2013 and the plant was commissioned on November 14, 2014. The plant is set to produce over 3,000 liters (792.5 US gal) of Audi e-diesel over the coming months. Audi is sunfire's exclusive partner in the automotive sector.

Over and above the partnership with sunfire, Audi has been active in the development of CO2-neutral fuels – Audi e-fuels – since 2009. The Audi e-gas plant in Werlte, Lower Saxony, already produces Audi e-gas (synthetic methane) in a comparable manner; drivers of the Audi A3 Sportback g-tron* can fill up on it using a special fuel card. Audi is also conducting joint research into the synthetic manufacture of Audi e-gasoline with Global Bioenergies, of France. In a further project, Audi has joined forces with the U.S. company Joule, which uses microorganisms to produce the synthetic fuels Audi e-diesel and Audi e-ethanol.

Fuel consumption of the models named above:

Audi A8:
Combined fuel consumption in l/100 km: 5.9 (39.9 US mpg)**;
Combined CO2 emissions in g/km: 155 (249.4 g/mi)**

Audi A3 Sportback g-tron:
CNG consumption in kg/100 kilometers: 3.3 – 3.2 (71.3 – 73.5 US mpg)**;
Combined fuel consumption in l/100 km: 5.2 – 5.0 (45.2 – 47.0 US mpg)**;
Combined CO2 emissions in g/km (CNG): 92 – 88 (148.1 – 141.6 g/mi)**;
Combined CO2 emissions in g/km (gasoline): 120 – 115 (193.1 – 185.1 g/mi)**

**The fuel consumption and the CO2 emissions of a vehicle vary due to the choice of wheels and tires. They not only depend on the efficient utilization of the fuel by the vehicle, but are also influenced by driving behavior and other non-technical factors.
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By John Beltz Snyder


See also: Audi spotted testing new S4 at the Nurburgring, Audi rolls out new A6 L E-Tron hybrid for China, Audi introduces Q7 E-Tron 2.0 TFSI in Shanghai.